arXiv:2605.16039v1 Announce Type: cross Abstract: The creation and exploration of new materials under extreme pressure-temperature conditions has become increasingly reliant on laser-heated diamond anvil cell (LHDAC) techniques, which provide direct access to previously unexplored regions of multinary phase diagrams. Whereas numerous high-pressure phases have been identified in situ, systematic recovery and post-synthesis physical property characterization of these materials remain significant challenges. In this work, we present the development of an integrated LHDAC synthesis and demonstrate a practical LHDAC-based synthesis workflow that enables stabilization and recovery of metastable intermetallic phases for subsequent structural and transport studies. Using this approach, we successfully achieved LHDAC synthesis of high-pressure MnSb2 and YbZn2 phases under moderate pressures. Synchrotron X-ray diffraction and spatial mapping confirm dominant formation of the targeted phases, whereas laboratory-based refinement quantifies phase fractions despite intrinsic microstrain and minor secondary phases. High-pressure transport measurements on recovered samples reveal tunable by pressure electronic instabilities in both systems. In MnSb2, pressure suppresses two high-temperature magnetic ordering anomalies, observed in transport, by 5 GPa and for higher pressures induces a new low-temperature feature that increases with further pressure increase. In hexagonal high-pressure YbZn2, an electronic reconstruction emerges at ~11 GPa, characterized by semiconducting-like behavior from ~ 30 K to 300 K and a broad low-temperature coherence crossover near 30 K. Our results establish LHDAC synthesis not only as a structural discovery tool, but also as an experimental platform for investigating correlated quantum states stabilized far from equilibrium thermodynamic conditions.
Science Journals
arXiv:2605.16207v1 Announce Type: new Abstract: Effective tutoring requires distinguishing optimal, valid but suboptimal, and incorrect student solutions, a distinction central to intelligent tutoring systems (ITS) but untested for LLM-based tutors. As LLMs are increasingly explored as conversational complements to ITS, evaluating their diagnostic precision is essential. We present a benchmark of seven LLM feedback agents in propositional logic using knowledge-graph-derived ground truth across 10,836 solution--feedback pairs and three feedback conditions. Models achieved near-ceiling performance on optimal steps but systematically over-rejected valid but suboptimal reasoning and over-validated incorrect solutions, precisely where adaptive tutoring matters most. These failures persisted across models regardless of solution context, suggesting architectural rather than informational limits. Moreover, accurate diagnosis did not reliably produce pedagogically actionable feedback, revealing a gap between diagnostic judgment and instructional effectiveness. Our findings suggest that LLMs are better suited for hybrid architectures where KG-grounded models handle diagnosis while LLMs support open-ended scaffolding and dialogue.
arXiv:2605.13246v2 Announce Type: replace Abstract: Reference counting bugs in Linux kernel drivers can lead to severe resource mismanagement and security vulnerabilities. We introduce DrvHorn, a novel automated tool to detect these bugs by reducing reference counting verification to an assertion checking problem leveraging the Linux driver interface. Through efficient modeling of the Linux kernel and aggressive program slicing, DrvHorn discovered 545 bugs, of which 424 were previously unknown, across all platform drivers in v6.6 Linux kernel, with a lower false positive rate of 29.9% compared to prior studies. To address the root causes of these newly discovered bugs, we submitted patches to the Linux kernel, and 45 of them were merged.
arXiv:2605.13788v2 Announce Type: replace Abstract: Active learning for machine-learning interatomic potentials (MLIPs) must address several challenges to be practical: scaling to large candidate pools, leveraging energy-force supervision, and maintaining robustness when candidate pools are biased relative to the target distribution. In this work, we jointly address these challenges. We first introduce a linearly scaling acquisition framework based on chunked feature-space posterior-variance shortlisting. By avoiding materialisation of the candidate and train set kernels, this approach enables screening of ~200k structures within hours and applies broadly to acquisition strategies that score candidates based on molecular similarity metrics. We then extend the Neural Tangent Kernel (NTK) to a force-aware setting via mixed parameter-coordinate derivatives, yielding a force NTK and a joint energy-force NTK that provide natural similarity metrics for vector-field prediction. We demonstrate the effectiveness of the joint energy-force NTK on the OC20 dataset, where force-aware acquisition is crucial: it achieves the lowest energy and force MAE and RMSE across all metrics and distribution splits. Across T1x, PMechDB, and RGD benchmarks, our force NTK methods remain competitive with established baselines while being significantly more efficient than committee-based approaches. Under a controlled candidate-pool shift case study on T1x, acquisition based on pretrained MLIP embeddings and NTKs remains robust, whereas committee-based methods exhibit higher variance. Overall, these results show that a single pretrained MLIP can enable scalable, force-aware, and distribution-robust active learning for foundation-model fine-tuning.
arXiv:2605.15240v1 Announce Type: cross Abstract: This paper investigates the critical role of eigenalignments between the kernel matrix and learning targets in achieving robust generalization in learning problems. We establish a direct connection between generalization performance in kernel methods and the estimation of eigenvectors and eigenvalues of matrices, offering a more intuitive understanding compared to prior work with minimal assumptions. We also show that, since the prediction task in KRR is essentially the weighted sum of eigenvectors/singular vectors, by analyzing how much error can be caused by perturbations to the kernel matrix, we can then derive a bound on this generalization error using the estimation stability of matrix eigenvalues and eigenvectors. Compared with previous work, our analysis concentrates on finite-sample settings and on the generalization error arising from having a suboptimal finite training set. Our findings reveal that in kernel methods, as long as the kernel is of high rank, the near-zero reconstruction error can be trivially obtained, implying that the reconstruction error will have limited predictive power for generalization. Finally, we establish a generalization bound from an eigenvalues/eigenvectors estimation perspective, showing that strong generalization requires increasing eigenvector alignment, eigenvalue magnitude, or gaps between consecutive eigenvalues.
arXiv:2605.16210v1 Announce Type: cross Abstract: The wolf note is an acoustic instability that occurs in large bowed string instruments when a strong body resonance interacts with the vibrating string, producing amplitude modulation and loss of tonal control. Various wolf suppressors - tuned mass dampers attached to the string or to the instrument body - are used in practice to mitigate this effect. In this paper, we propose a mathematical model describing the coupled dynamics of a string and a two-dimensional body equipped with one or two wolf suppressors. Both string and body include elastic (second-order) and stiffness (fourth-order) contributions and can be excited either by plucking or bowing. Three performance indicators are introduced: The first one perceives the wolf-tone appearance, the second one quantifies the attenuation of the notes possibly caused by the wolf suppressor, and the third one measures the acoustic fidelity (in terms of spectrum) with respect to the original instrument. The proposed numerical tests give insights about optimal tuning and placement of one or two suppressors, achieving effective wolf-note suppression while preserving as much as possible the global tonal balance.
arXiv:2605.16253v1 Announce Type: new Abstract: Ray tracing (RT) is a 3D graphics technique that offers highly realistic visuals. It is becoming prominent and accessible as GPU vendors have integrated dedicated ray tracing acceleration hardware. However, tracing millions of rays through 3D scenes consisting of high numbers of triangles in real time is challenging and requires expensive hardware. The main bottleneck in RT workloads is the expensive Bounding Volume Hierarchy (BVH) traversal task, which is a large tree structure that encodes the 3D scene. BVH traversal is a memory-bound problem, as the GPU threads spend most of their time reading tree node data from memory. In this work, we attack the memory latency bottleneck of ray tracing through prefetching. We propose a novel hardware prefetcher, named Tree Traversal Prefetcher (TTP), for ray tracing. The main idea is to leverage the existing tree traversal stack in the RT units for highly accurate prefetching. In particular, TTP prefetches nodes using the addresses already available on the hardware traversal stacks of each thread. For DFS (Depth-first search) based traversal, prefetches are generated when nodes are being popped consecutively from the traversal stack, potentially corresponding to upward traversal through the tree. We evaluate TTP on a cycle-level simulator, Vulkan-sim 2.0, and show that it achieves 1.48x speedup on average (up to 1.89x) compared to the baseline, with nearly negligible hardware overhead. TTP achieves 98.92% average L1 accuracy, which is the ratio of the prefetched blocks being actually referenced by demand loads. The coverage, computed as the ratio of L1 miss reduction over baseline L1 misses, is 31.54%, correlating well with the achieved speedup.
arXiv:2605.15225v1 Announce Type: cross Abstract: Biologically-inspired AI agent frameworks claim reliability benefits through structural guarantees adapted from gene regulatory networks, immune systems, and metabolic control. These claims are rarely tested empirically against simpler alternatives. We present three deep benchmarks: metabolic priority gating, autoinducer-based quorum sensing, and Bayesian stagnation detection, each comparing a biologically-grounded implementation against a naive non-biological alternative and an ablated control, across 1,000 trials per seed and 10 seeds (10M+ data points total).
arXiv:2605.16135v1 Announce Type: cross Abstract: Inter-core skew (ICS), the differential group delay between cores of a multicore fiber (MCF), is a critical parameter for both classical space-division multiplexed communications and quantum photonic networks. We present a high-precision measurement of ICS in a commercially available four-core fiber using two-photon Hong--Ou--Mandel (HOM) interference in a fiber-integrated $4\times4$ multiport beam splitter. By extracting the center position of HOM interference dips and peaks across all twelve core-pair combinations, we obtain individual ICS values with a demonstrated precision of $\pm0.11\,$ps, limited by the delay-stage positioning uncertainty. The root-mean-square ICS grows as $\sigma_\tau(L) = \kappa\sqrt{L}+c$ with $\kappa = 48.7 \pm 2.5\,\mathrm{ps}/\!\sqrt{\mathrm{km}}$ and $c = 9.76 \pm 1.2\,$ps, over fiber lengths from $7.7\,$m to $1300\,$m. This first direct validation of the stochastic random-walk scaling across a length range spanning laboratory to field-deployed scales was made possible by HOM's immunity to first-order path fluctuations, which renders classical interferometric methods impractical for long installed fibers. The demonstrated $\pm0.11\,$ps precision represents a $\sim\!180$-fold improvement over correlation optical time-domain reflectometry (C-OTDR), the standard method for long-fiber ICS characterization. Fisher information analysis establishes a fundamental Cram\'er--Rao precision limit in the femtosecond range, indicating further improvement is achievable with better delay control. These results establish a practical platform for characterising timing uniformity in MCF-based networks for both quantum and classical space-division multiplexed applications.
arXiv:2605.16037v1 Announce Type: cross Abstract: Fast and Relaxed Vector Fitting (FRVF) is a frequency-domain system identification approach that has been widely adopted in electrical system modelling, while its application to mechanical systems has remained relatively unexplored. In this work, FRVF is reformulated for the identification of structural modal parameters of an aircraft based on Ground Vibration Test (GVT) data within a Multi-Input Multi-Output (MIMO) framework. The proposed procedure consists of three stages: (i) rational approximation of frequency response functions via an enhanced input-stacking strategy, (ii) identification of system poles from the resulting rational model, and (iii) estimation of modal parameters from the extracted poles and associated residues. The methodology is first numerically validated on a MIMO beam model, with particular emphasis on accuracy and robustness under increasing measurement noise. Subsequently, experimental validation is conducted using GVT data from the BAE Systems Hawk T1A aircraft. The results obtained demonstrate a level of performance comparable to that achieved by existing methods. Overall, the extended MIMO formulation of FRVF exhibits high accuracy and strong robustness to measurement noise, highlighting its suitability for application in GVT-based modal analysis.
arXiv:2604.08426v4 Announce Type: replace Abstract: With the growing demand for long-context LLMs across a wide range of applications, the key-value (KV) cache has become a critical bottleneck for both latency and memory usage. Recently, KV-cache offloading has emerged as a promising approach to reduce memory footprint and inference latency while preserving accuracy. Prior evaluations have largely focused on tasks that do not require extracting large amounts of information from the context. In this work, we study KV-cache offloading on context-intensive tasks: problems where the solution requires looking up a lot of information from the input prompt. We create and release the Text2JSON benchmark, a highly context-intensive task that requires extracting structured knowledge from raw text. We evaluate modern KV offloading on Text2JSON and other context-intensive tasks and find significant performance degradation on both Llama 3 and Qwen 3 models. Our analysis identifies two key reasons for poor accuracy: low-rank projection of keys and unreliable landmarks, and proposes a simpler alternative strategy that significantly improves accuracy across multiple LLM families and benchmarks. These findings highlight the need for a comprehensive and rigorous evaluation of long-context compression techniques.
arXiv:2605.15426v1 Announce Type: cross Abstract: Entanglement in continuous-variable Gaussian systems is a key resource, and common reservoirs can both suppress and generate correlations. Existing work focused on pre-entangled states or Markovian baths, leaving open whether separable squeezed inputs entangle in structured environments or under modulation. We study two bosonic modes coupled to a common reservoir, each initialized in a separable squeezed vacuum. Dynamics are analyzed utilizing Gaussian covariance methods, evolved under approximate Non-Markovian quantum state diffusion (QSD), finite-temperature pseudomode embeddings, and Bures-based non-Markovian diagnostics. We identify three mechanisms absent in Markovian dynamics: (1) A detuning condition that freezes entanglement trajectories across reservoir correlation times; (2) birth, death, and revival of entanglement from orthogonal inputs; and (3) integer-locked beating with square-wave oscillations produced by periodic detuning. All mechanisms persist at finite temperature, with deviations bounded within 5% in cryogenic regimes and 20% at moderate occupations. These deviation bounds align with cryogenic cavity, phononic, and optomechanical platforms, where structured spectral densities and detuning modulation are already accessible. Structured reservoirs are shown to emerge as tunable entanglement resources for continuous-variable quantum technologies.
arXiv:2605.15667v1 Announce Type: cross Abstract: On a finite outcome space, the canonical Gibbs distribution is usually obtained by maximizing Shannon entropy at fixed mean of an externally supplied energy functional. This paper studies the finite-state consequences of a ratio-cost construction instead: after adopting the normalized d'Alembert degree-two closure called the Recognition Composition Law (RCL), with unit log-curvature calibration at the reference ratio, the continuous nontrivial positive branch is $J(x)=\tfrac12(x+x^{-1})-1=\cosh(\log x)-1$. Given the induced cost vector $X_\omega=J(r_\omega)$, multinomial counting and convex duality recover the finite-state Gibbs weights and the identity $F_{\mathrm{R}}(q)-F_{\mathrm{R}}(p)=T_{\mathrm{R}}\,D_{\mathrm{KL}}(q\Vert p)$; the entropy-maximization steps are classical once the cost is fixed. New technical content includes a non-asymptotic Stirling bound and soft-shell constrained-type theorems for real-valued costs. A three-state example compares the Gibbs law to squared-log, affinity-as-energy, and Tsallis alternatives at the same cost vector and mean-cost constraint, with sample-size power calculations at fixed RCL ground truth. The framework is conditional on axioms (A1)--(A3) and restricted to finite outcome spaces with strictly positive weights; it does not derive the composition law from a more primitive principle.
arXiv:2605.15438v1 Announce Type: cross Abstract: The fluidic pinball presents a significant benchmark for nonlinear flow control, managing the complex interactions of three cylinder wakes. This study addresses the stabilization of the fluidic pinball to its unstable steady-state solution using a model-based nonlinear feedback strategy. We propose a framework that combines interpolatory model order reduction (IMOR) with the quadratic-quadratic regulator (QQR), a feedback control methodology that is specifically suited to the quadratic nonlinearity of the Navier-Stokes equations. A finite element model (FEM) of the problem coupled with IMOR is used to produce a reduced-order model (ROM) that accurately represents the input-output dynamics of the actuated wake. The performance of the QQR control is evaluated against the traditional linear feedback control for two different Reynolds numbers, $Re_D = 30$ and $Re_D = 50$. At $Re_D = 30$, the QQR controller is able to stabilize the wake and reaches the desired performance criteria 40.1\% faster than using a linear feedback controller. More significantly, at $Re_D = 50$, the QQR controller successfully stabilizes the wake, whereas the linear controller fails to overcome the nonlinearity of the flow. The QQR control effectively suppresses vortex shedding, resulting in the elimination of lift oscillations and a reduction in the drag coefficient. These results demonstrate that the IMOR-QQR framework provides an effective model-based control strategy that can manage nonlinear hydrodynamic instabilities in such complex wake flows.
arXiv:2507.01679v3 Announce Type: replace Abstract: Existing LLMs-post-training techniques are broadly categorized into supervised fine-tuning (SFT) and reinforcement fine-tuning (RFT). Each paradigm presents a distinct trade-off: (1) SFT excels at mimicking demonstration data, but can lead to problematic generalization as a form of behavior cloning. (2) Conversely, RFT can significantly enhance a model's performance but is prone to learning unexpected behaviors, and its performance is sensitive to the initial policy. In this paper, we propose a unified view of these methods and introduce Prefix-RFT, a hybrid approach that synergizes learning from both demonstration and exploration. Using mathematical reasoning problems as a test bed, we empirically demonstrate that Prefix-RFT is simple yet effective. Not only does it surpass the performance of standalone SFT and RFT, but it also outperforms parallel mixed-policy RFT methods. Our analysis highlights the complementary nature of SFT and RFT, validating that Prefix-RFT effectively harmonizes them. Further ablation studies confirm the method's robustness to variations in the quality and quantity of demonstration data.
arXiv:2605.16205v1 Announce Type: new Abstract: Deploying compound LLM agents in adversarial, partially observable sequential environments requires navigating several design dimensions: (1) what the agent sees, (2) how it reasons, and (3) how tasks are decomposed across components. Yet practitioners lack guidance on which design choices improve performance versus merely increase inference costs. We present a controlled study of compound LLM agent design in CybORG CAGE-2, a cyber defense environment modeled as a Partially Observable Markov Decision Process (POMDP). Reward is non-positive, so all configurations operate in a failure-mitigation mode. Our evaluation spans five model families, six models, and twelve configurations (3,475 episodes) with token-level cost accounting. We vary context representation (raw observations vs. a deterministic state-tracking layer with compressed history), deliberation (self-questioning, self-critique, and self-improvement tools, with optional chain-of-thought prompting), and hierarchical decomposition (monolithic ReAct vs. delegation to specialized sub-agents). We find that: (1) Programmatic state abstraction delivers the largest returns per token spent (RPTS), improving mean return by up to 76% over raw observations. (2) Distributing deliberation tools across a hierarchy degrades performance relative to hierarchy alone for all five model families, reaching up to 3.4$\times$ worse mean return while using 1.8-2.7$\times$ more tokens. We call this destructive pattern a deliberation cascade. (3) Hierarchical decomposition without deliberation achieves the best absolute performance for most models, and context engineering is generally more cost-effective than deliberation. These findings suggest a design principle for structured adversarial POMDPs: invest in programmatic infrastructure and clean task decomposition rather than deeper per-agent reasoning, as these strategies can interfere when combined.
arXiv:2605.12581v1 Announce Type: cross Abstract: Synthesising autonomous agents that can navigate uncertain environments while adhering to complex temporal constraints remains a fundamental challenge. While Linear Temporal Logic (LTL) provides a rigorous language for specifying such tasks, the inherent undecidability of qualitatively verifying LTL satisfaction in partially observable Markov decision processes renders quantitative synthesis difficult, especially when designing reliable reward signals for approximate solvers. In this paper, we bridge this gap with a novel, sound reward-shaping mechanism that dynamically generates belief-dependent rewards grounded in certified LTL satisfaction. By integrating this mechanism into an enhanced Monte Carlo Planning framework, we empower agents to navigate the `fog' of partial observability with a search process focused on maximising verifiable success. Our experiments demonstrate that this approach not only thrives in scenarios where existing solvers fail but also maintains effectiveness and scalability across diverse benchmark domains.
arXiv:2605.06475v1 Announce Type: cross Abstract: We introduce a probabilistic approach for dating historical manuscript pages from visual features alone. Instead of aggregating centuries into classes as is standard in the previous literature, we pose dating as an evidential deep regression problem over a continuous year axis, allowing our neural network to output a full predictive distribution with decomposed aleatoric and epistemic uncertainty in a single forward pass. Our architecture combines an EfficientNet-B2 backbone with a Normal-Inverse-Gamma (NIG) output head trained with a joint negative-log-likelihood and evidence-regularization objective. On the DIVA-HisDB benchmark (150 pages, 3 medieval codices, 151,936 patches), our model scores a test MAE of 5.4 years, well below the 50-year century-label supervision granularity, with 93\% of patches within 5 years and 97\% within 10 years. Our approach achieves \textbf{PICP=92.6\%}, the best calibration among all compared methods, in a single forward pass, outperforming MC Dropout (PICP=88.2\%, 50 passes) and Deep Ensembles (PICP=79.7\%, 5 models) at $5\times$ lower inference cost. Uncertainty decomposition shows aleatoric uncertainty is a strong predictor of dating error (Spearman $\rho=0.729$), and a selective prediction about the most certain 20\% of patches can provide \textbf{0.5 years MAE}. We show that predicted uncertainty increases as image degradation worsens, spatial decomposition maps explain which script regions cause aleatoric uncertainty, and page-level aggregation reduces MAE to 4.5 years with $\rho=0.905$ between uncertainty and page-level error.
arXiv:2605.16206v1 Announce Type: new Abstract: We present fully kinetic two-dimensional, three-velocity-component (2D3V) PIConGPU simulations of a three-beam direct-drive interaction with a 15 $\mu$m solid-density cryogenic hydrogen cylinder, establishing a predictive numerical baseline for the operational DRACO ($\tau=30$ fs) and upcoming PENELOPE ($\tau=150$ fs) laser facilities at HZDR. The simulations resolve charge-separation fields on the order of 3 TV/m and reveal a robust kinematic bifurcation of the accelerated population into a fast (1-5 MeV) ion beam and a slower bulk (1-100 keV) flow. We demonstrate analytically and numerically that the charge-separation front ($v_{hb}$) is an intrinsically non-quasi-neutral electrostatic double layer that lies outside the closure assumptions of radiation-hydrodynamic models. A simple $2v_{hb}$ reflection scaling derived directly from the front trajectory tracks the centroid of the constant-energy fast-ion band under the impulsive 30 fs driver and the time-varying upper edge of the swept fast-ion band under the sustained 150 fs driver, across both intensities ($a_{0}=12.7$ and 22.0), establishing this non-thermal mechanism as the dominant acceleration pathway. We then scan an external axial magnetic field from 0 T to 10 kT. Laboratory-achievable 20 T fields leave all macroscopic observables unchanged; fields at the kT scale progressively magnetise the MeV hot-electron population, quench the laser-driven charge-separation mechanism, suppress the fast-ion band, and more than double the net-inward compression time of the short-pulse driver-while extending the outer target envelope. A geometric equivalence argument maps these kT-scale results onto larger-diameter cryogenic hydrogen jets.
arXiv:2605.16127v1 Announce Type: new Abstract: While multi-modal 3D semantic occupancy prediction typically enhances robustness by fusing camera and LiDAR inputs, its effectiveness is fundamentally constrained by environmental variability. Specifically, camera sensors suffer from severe low-light degradation, while LiDAR sensors encounter significant backscatter noise during heavy precipitation. These adverse conditions create a modality trust problem, as static fusion strategies fail to adaptively re-weight inputs when a specific sensor becomes unreliable. To address this, we propose a VLM-assisted framework leveraging the pre-trained CLIP latent space to guide multi-sensor integration via linguistic environmental cues. We utilize a parameter-efficient adapter to align weather-specific text embeddings with sensor features, coupled with a gating strategy that decomposes environmental uncertainty into two factors: visibility and illumination. This enables the model to dynamically modulate the fusion ratio - prioritizing semantic camera features in clear daylight and shifting to geometric LiDAR priors during rainy nights. Evaluations on the nuScenes dataset demonstrate the versatility of our approach, as implementing our proposed framework on the OccMamba and M-CONet architectures achieves mIoU scores of 26.3 and 21.1, respectively, significantly outperforming their traditional baselines.
arXiv:2605.16257v1 Announce Type: new Abstract: Achieving human-level manipulation requires dexterous robotic hands capable of complex object interactions. Advancing such capabilities further demands standardized benchmarks for systematic evaluation. However, existing dexterous benchmarks lack tasks that reflect the unique manipulation capabilities of dexterous hands over parallel grippers, as well as comprehensive evaluation pipelines. In this paper, we present DexJoCo, a benchmark and toolkit for task-oriented dexterous manipulation, comprising 11 functionally grounded tasks that evaluate tool-use, bimanual coordination, long-horizon execution, and reasoning. We develop a low-cost data collection system and collect 1.1K trajectories across these tasks, with support for domain randomization to assess robustness. We benchmark modern models under diverse settings, including visual and dynamics randomization, multi-task training, and action-head adaptation. Through extensive empirical analysis, we identify several important insights and common limitations of current policies in dexterous manipulation, highlighting key challenges for future research in dexterous hand robot learning. Project page available at: https://dexjoco.github.io
arXiv:2605.16012v1 Announce Type: cross Abstract: BEDT-TTF-based organic conductors host a number of ground states, tuned by electron repulsion from Mott and charge ordered insulators to superconductors. Knowing charge distribution on the molecular sites in the insulating state of these materials is a key to understanding the origin of these ground states. We survey and discuss the C=C stretching modes in BEDT-TTF based molecular conductors. These molecular vibrations are extremely crucial in characterization of charge-ordered insulators, and are recently linked to superconductivity in some compounds. Focusing on the known examples of BEDT-TTF$^{+0.5}$ salts, we analyse the reliability of the C=C stretching modes for the determination of charge ordering and absolute site charge. Considering the charge-ordered states, a prominent shift in frequency of 141 cm$^{-1}$ per elementary charge $e$ for $\nu_{27}(b_{1u})$ and 98 cm$^{-1}$$e$ for $\nu_2$($a_g$) can be clearly realised, however, the distribution resulting from different compounds span over 20 cm$^{-1}$. For nominal BEDT-TTF$^{+0.5}$ compounds, the distribution of the resonance also extends around 20 cm$^{-1}$, yielding an unexpected large uncertainty of $\Delta\rho~\approx~(~\pm~0.045)e$, which is presumably due to the influence of small differences in the structure. This highlights the limitations of charge-frequency relations to detect small deviations in absolute charge values on molecular lattice sites, and emphasises on the use of the relations to estimate charge-ordering, rather than absolute site charge.
arXiv:2605.15456v1 Announce Type: cross Abstract: Solving imaging inverse problems has usually been addressed by designing proper prior models of the underlying signal. However, minimizing the data fidelity term poses significant challenges due to the ill-conditioned sensing matrix caused by physical constraints in the acquisition system. Thus, preconditioning techniques have been adopted in classical optimization theory to address ill-conditioned data-fidelity minimization by transforming the algorithm gradient step to achieve faster convergence and better numerical stability. We extend the preconditioning concept beyond convergence acceleration and use it to improve reconstruction quality. We introduce DIPA: Distilled Preconditioned Algorithms, where a preconditioning operator (PO) is optimized using teacher-guided distillation criteria. Unlike standard model-compression KD, the teacher and student differ by the sensing operators available during reconstruction: the teacher uses a simulated, better-conditioned, and more informative sensing matrix, whereas the student uses the physically feasible sensing matrix. We design different distillation loss functions to transfer different properties of the teacher algorithm to the preconditioned student. The PO can be linear (L-DIPA), allowing interpretability, or non-linear (N-DIPA), parametrized by a neural network, offering better scalability. We validate the proposed PO design across several imaging modalities, including magnetic resonance imaging, compressed sensing, and super-resolution imaging.
arXiv:2510.02278v2 Announce Type: replace Abstract: Modeling traffic dynamics is a critical challenge for urban computing, with applications from real-time traffic management to infrastructure planning. However, progress in this area is fundamentally constrained by a lack of large-scale public datasets that capture the subtle properties of real city road networks. Existing benchmarks are often limited by their small scale, reliance on sparse highway traffic sensors, absence of true road connectivity information, and lack of information about road properties. To address this issue, we introduce datasets representing fine-grained road networks of two major cities, which are unique in their scale (up to 100,000 road segments), use of real road connectivity, presence of time series measurements for both traffic speed and volume at a 5-minute resolution, and inclusion of rich static road attributes. These datasets enable in-depth analysis of spatiotemporal traffic patterns and can serve as benchmarks for various ML applications. As a practical demonstration of the utility of our datasets and the challenges they present, we use them for the task of traffic forecasting. The size of the real-world road networks in our datasets reveals significant scalability issues in current traffic forecasting models. To address them, we propose a simple and efficient baseline that not only scales to large road graphs but also achieves forecasting performance competitive with other established spatiotemporal models. We hope that the proposed datasets will serve as a foundational resource for a broad range of research in traffic modeling, urban computing, and smart city development.
arXiv:2507.14200v2 Announce Type: replace Abstract: Existing multi-LLM collaboration systems often encounter scalability challenges when integrating new LLMs and tasks, leading to suboptimal performance. To address this, we propose SMCS, a Scalable Multi-LLM Collaboration System designed to effectively coordinate multiple open-source LLMs. The system consists of two core components: a Retrieval-based Prior Selection (RPS) module, which dynamically selects the most suitable LLMs for each input, and an Exploration-Exploitation-Driven Posterior Enhancement (EPE) module, which fosters response diversity and selects high-quality outputs through a hybrid scoring mechanism. Experiments on eight mainstream benchmarks validate the effectiveness of our system: by integrating fifteen open-source LLMs, SMCS outperforms prevailing closed-source LLMs, e.g., GPT-4.1(+5.36%) and GPT-o3-mini(+5.28%) across multiple tasks. Remarkably, it even exceeds the average of best results on different datasets with open-source LLMs (+2.86%), significantly advancing the empirical performance frontier of open-source collaboration. The code is released at https://github.com/magent4aci/SMCS.